電流遮断法を用いたPCFCの過電圧損の分離評価法の検討
電流遮断法を用いたPCFCの過電圧損の分離評価法の検討
カテゴリ: 論文誌(論文単位)
グループ名: 【A】基礎・材料・共通部門
発行日: 2022/07/01
タイトル(英語): Study on PCFC Total Voltage Loss Analysis by Current Interruption Technique to Separate IR Drop and Overvoltage
著者名: 椎根 健太(日本大学理工学部電気工学科),辻 健太郎(日本大学理工学部電気工学科),吉川 将洋(日本大学理工学部電気工学科)
著者名(英語): Kenta Shiine (Major of Electrical Engineering, Graduate School of Science and Technology, Nihon Universiy), Kentaro Tsuji (Major of Electrical Engineering, Graduate School of Science and Technology, Nihon Universiy), Masahiro Yoshikawa (Major of Electrical Engineering, Graduate School of Science and Technology, Nihon Universiy)
キーワード: 固体酸化物形燃料電池(SOFC),PCFC,電流遮断法,オーミック損,過電圧 solid oxide fuel cell,protonic ceramic fuel cell,current interruption technique,ohmic loss,over voltage
要約(英語): The voltage loss factors in Protonic Ceramic Fuel Cell (PCFC) are caused by anode polarization, cathode polarization and voltage drop by internal resistance. In this paper, an analytical method which divides the total voltage loss into the ohmic loss, anode overvoltage, and other overvoltage by current interruption technique has been reported. Firstly, applying the develop method to analysis of voltage loss factors, the number of RC parallel elements can be determined as seven from the voltage relaxation waveform without assuming the number of elements in advance. Secondly, it was revealed that the overvoltage η1 which is the smallest time constant in seven elements is caused by the hydrogen concentration in the fuel and steam concentration in the Air electrode. Moreover, it was revealed that and the overvoltage η3 and η4 are caused by the oxygen concentration and steam concentration in the air electrode. Especially, η5 is caused by oxygen in air electrode. On the other hands, it could not clearly separate the overvoltage η2 which might be caused by the hydrogen, oxygen, and steam concentration in the fuel electrode but also η6 to η7 in this study.
本誌: 電気学会論文誌A(基礎・材料・共通部門誌) Vol.142 No.7 (2022) 特集:電気電子工学関連分野における教育フロンティア
本誌掲載ページ: 321-327 p
原稿種別: 論文/日本語
電子版へのリンク: https://www.jstage.jst.go.jp/article/ieejfms/142/7/142_321/_article/-char/ja/
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