電気化学的手法によるポリピロールの形態制御
電気化学的手法によるポリピロールの形態制御
カテゴリ: 論文誌(論文単位)
グループ名: 【A】基礎・材料・共通部門
発行日: 2011/06/01
タイトル(英語): Morphological Control of Polypyrrole based on Electrolysis Technique
著者名: 小野田 光宣(兵庫県立大学大学院工学研究科),岡田 昌之(兵庫県立大学大学院工学研究科),多田 和也(兵庫県立大学大学院工学研究科)
著者名(英語): Mitsuyoshi Onoda (University of Hyogo, Graduate School of Engineering), Masayuki Okada (University of Hyogo, Graduate School of Engineering), Kazuya Tada (University of Hyogo, Graduate School of Engineering)
キーワード: 電気化学的重合,導電性高分子,ポリピロール,成長形態制御,節点数制御 electrolysis polymerization method,conductive polymer,polypyrrole,conrol of growth morphology,node number control
要約(英語): By controlling electrochemical polymerization conditions conductive polymers have been fabricated not on the electrode but on the bottom of the electrochemical cell or in the electrolyte with needle-plane electrode structure. Poly(pyrrole), PPy with a fractal form has been successfully prepared by an electrochemical polymerization technique. The growth form of conductive polymer has been investigated as the effect of the composition of the electrolyte, that is, the kind of solvent, the kind of supporting electrolyte, and the monomer, and the difference in the concentrations, especially the effect of basic properties of the solvent such as the polarity (relative polarity measure), basicity (nucleophilic nature), that is, donor number, in addition, viscosity, relative permittivity, etc.
本誌: 電気学会論文誌A(基礎・材料・共通部門誌) Vol.131 No.6 (2011) 特集:電気電子絶縁材料システムシンポジウム
本誌掲載ページ: 433-438 p
原稿種別: 論文/日本語
電子版へのリンク: https://www.jstage.jst.go.jp/article/ieejfms/131/6/131_6_433/_article/-char/ja/
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